Egyptian researchers develop new photovoltaic cell.

Researchers from the Central Metallurgical Research and Development Institute (CMRDI) in Egypt have fabricate an inverted perovskite solar cell with a new type of hole transport layer (HTM) based on silver thiocyanate (AgSCN). The scientists aim to replace commonly used hole transport materials like PEDOT:PSS and copper thiocyanate (CuSCN) with AgSCN.

“CuSCN's advantages lie in the fact that it can serve as both a hole transport layer and a source of Cu doping, while AgSCN, with its greater resistivity, may serve just as a source of Ag doping with a slower diffusion rate,” the scientists explained, noting that AsSCN is also better at transferring charges between HTL and perovskite layer compared to PEDOT:PSS.

The group built the cell with an indium tin oxide (ITO) substrate, an electron transport layer (ETL) based on AgSCN, an absorber based on a type of lead-halide perovskite known as methylammonium lead iodide (MAPbI3), a phenyl-C61-butyric acid methyl ester (PCBM) layer, a bathocuproine (BCP) buffer layer, and a silver (Ag) metal contact.

The academics deposited the AgSCN thin film in a dry glove box with relative humidity between 25% and 30% at least 30 minutes before the deposition of the perovskite layer started. They then deposited the perovskite layer on the active layer on the HTL via spin coating at 4,000 rpm for 30 seconds. The performance of the solar cell was compared to a reference device constructed with an HTM relying on PEDOT:PSS.